Dibutylamine → 1-Di-n-butylamino-5,5,7,7-tetramethyl-2-octene

HRID 249033

반응식

HRID 249033 반응식
Cl[CH2:2][CH:3]=[CH:4][CH2:5][C:6]([CH3:13])([CH3:12])[CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9].[CH2:14]([NH:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:15][CH2:16][CH3:17].[O-2].[Mg+2]>C1COCC1.CCCCCC>[CH2:14]([N:18]([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:2][CH:3]=[CH:4][CH2:5][C:6]([CH3:13])([CH3:12])[CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9])[CH2:15][CH2:16][CH3:17]

참가 물질

6

반응물 3

HCID 8148DibutylamineHCID 1359701-Chloro-5,5,7,7-tetramethyl-2-octeneHCID 6850729Magnesium monoxide

생성물 1

HCID 538384691-Di-n-butylamino-5,5,7,7-tetramethyl-2-octene

시약·촉매·용매 2

HCID 8028Tetrahydrofuran용매HCID 8058Hexane용매

실험 절차

10 g (49.5 mmol) of 1-chloro-5,5,7,7-tetramethyl-2-octene, 64 g (495 mmol) of di-n-butylamine and 10 g (248 mmol) of magnesium oxide in 30 ml of THF are refluxed for 4.5 h. The mixture is taken up in 200 ml of hexane, extracted twice with 5% strength methanolic NaOH and once with water and dried at 30° C./1 mbar. Yield: quantitative.

후처리

  1. extractionextracted twice with 5% strength methanolic NaOH and once with water
  2. customdried at 30° C./1 mbar

출처 및 근거

ORD 기록
ord-84a14235b1cd492588451c9f8e12a505
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05212248

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