Azobisisobutyronitrile → 2-Phenylethenesulfonic acid

HRID 254137노트

반응식

HRID 254137 반응식
[CH:1]([S:9]([O-:12])(=[O:11])=[O:10])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[Na+].FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.N(C(C)(C)C#N)=NC(C)(C)C#N>CS(C)=O>[CH:1]([S:9]([OH:12])(=[O:10])=[O:11])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

5

반응물 3

HCID 6547AzobisisobutyronitrileHCID 2782409Perfluorooct-1-ene2회HCID 53627496Sodium styrenesulfonate

생성물 1

HCID 748642-Phenylethenesulfonic acid

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매2회

실험 절차

19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of branched perfluorooctene (heptafluoro-3,3-bis(trifluoromethyl)-1-hexene) are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the branched perfluorooctene (5, 10, and 20 wt %).

후처리

  1. temperaturewith heating
  2. customThe monomers are polymerized for 24 hours or more

출처 및 근거

ORD 기록
ord-edf865c9d65745a9ab3f6d0f1a499dd6
출처 데이터셋
uspto-grants-2011_01
특허 번호
US07875208B2

반응 노트

불러오는 중…