Sodium Hydroxide → Beta-D-Glucose 6-phosphate

HRID 256704

반응식

HRID 256704 반응식
[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C@@H:10]([OH:13])[CH:11]=[O:12])([O-:4])([O-:3])=[O:2].[Ba+2].[OH-].[Na+].[BH4-].[Na+]>O>[CH2:6]([O:5][P:1]([OH:3])([OH:4])=[O:2])[C@H:7]1[O:16][C@@H:11]([OH:12])[C@H:10]([OH:13])[C@@H:9]([OH:14])[C@@H:8]1[OH:15]

참가 물질

5

반응물 3

HCID 14798Sodium HydroxideHCID 111125Barium glucose 6-phosphateHCID 4311764Sodium borohydride

생성물 1

HCID 439427Beta-D-Glucose 6-phosphate

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
45 °C

실험 절차

To 10 ml of the aminated gel obtained in Preparation Example 2 were added, first 10 ml of water, next 1 g of barium glucose-6-phosphate, to which 0.5 ml of 2M NaOH was further added and the mixture was maintained at 45° C. for 1 hour. After 0.1 g of NaBH4 was added thereto, the mixture was allowed to stand at room temperature for 24 hours. After the reaction was completed, the gel was filtered off from the reaction mixture and washed with water to give a cellulose gel with immobilized glucose-6-phosphate. The amount of the introduced anionic functional group derived from the immobilized glucose-6-phosphate was 10 μmol to 1 ml of the adsorbent.

후처리

  1. additionwere added
  2. filtrationthe gel was filtered off from the reaction mixture
  3. washwashed with water

출처 및 근거

ORD 기록
ord-bed67b7f3eff4616bf94a00e5dfb7fe8
출처 데이터셋
uspto-grants-1993_11
특허 번호
US05258503

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