Potassium Carbonate → HCID 22916411, 화합물

HRID 265417

반응식

HRID 265417 반응식
[C:1]1([N:7]2[C:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=3)=[C:10]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)[NH:9][C:8]2=[O:24])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][C:34]([O:36]CC)=[O:35].C(=O)([O-])[O-].[K+].[K+].[OH-].[Na+]>CC(=O)CC.C(O)C.O>[C:1]1([N:7]2[C:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=3)=[C:10]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)[N:9]([CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][C:34]([OH:36])=[O:35])[C:8]2=[O:24])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

8

반응물 4

HCID 11430Potassium CarbonateHCID 14798Sodium HydroxideHCID 560317Disodium acetylideHCID 6285441,4,5-Triphenyl-1,3-dihydro-2H-imidazol-2-one

생성물 1

HCID 22916411HCID 22916411, 화합물

시약·촉매·용매 3

HCID 702Ethanol용매HCID 962Water용매HCID 6569Methyl Ethyl Ketone용매

실험 절차

1,4,5-Triphenylimidazol-2-one was treated with ethyl 9-bromononanoate and potassium carbonate in butanone, followed by sodium hydroxide in ethanol and water, to give after work-up the title compound, m.p. 123°-124° C., Found:C, 76.9;H, 6.9;N, 5.7%;C30H32N2O3 requires: C, 76.9; H, 6.9; N, 6.0%

출처 및 근거

ORD 기록
ord-875414e9de0d4c98b502bba67e1cb404
출처 데이터셋
uspto-grants-1997_07
특허 번호
US05648373

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