Aminoacetaldehyde → 1-(alpha-Phenyl-o-tolyl)imidazole
반응식
[C:1]1([CH2:7][C:8]2[C:9](=[CH:11][CH:12]=[CH:13][CH:14]=2)[NH2:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH:15](OC)(OC)OC.[NH2:22][CH2:23][CH:24]=O>C(COC)OC.[Ti](Cl)(Cl)(Cl)Cl>[C:1]1([CH2:7][C:8]2[CH:14]=[CH:13][CH:12]=[CH:11][C:9]=2[N:10]2[CH:24]=[CH:23][N:22]=[CH:15]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1참가 물질
6
실험 절차
In the manner given in Example 1, α-phenyl-0-toluidine is reacted first with trimethyl orthoformate; the resulting product is reacted with aminoacetaldehyde, dimethyl acetal, and the resulting product of this reaction is heated with titanium tetrachloride in monoglyme to give 1-(α-phenyl-0-tolyl)imidazole.
출처 및 근거
- ORD 기록
- ord-aa4b3d1a327b410b88fda1fb97a23e75
- 출처 데이터셋
- uspto-grants-1976_03
- 특허 번호
- US03941802
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