Benzyl Chloride → Benzyl Phenyl Ether
반응식
O.O.O.[C:4]1([O-:10])[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[Na+].[CH2:12](Cl)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>CO>[CH2:12]([O:10][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1참가 물질
4
실험 절차
A mixture of sodium phenolate trihydrate (10.2 g; 60 mmole) and benzyl chloride (6.4 ml; 56 mmole) in methanol (150 ml) was pumped through the system (15 ml/minute; 146°-7° C.; 1000-1050 kPa). The MeOH was rotary evaporated off and the residue recrystallised from EtOH to afford colourless needles of phenyl benzyl ether (6.9 g; 67% yield), m.p. 36°-36.3° C.
후처리
- customwas pumped through the system (15 ml/minute; 146°-7° C.; 1000-1050 kPa)
- customThe MeOH was rotary evaporated off
- customthe residue recrystallised from EtOH
출처 및 근거
- ORD 기록
- ord-80ea20519fd44352987956fe78cc4b12
- 출처 데이터셋
- uspto-grants-1995_02
- 특허 번호
- US05387397
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