Triphenylphosphine → [(E)-cinnamyl]-triphenyl-phosphonium chloride

HRID 274192

반응식

HRID 274192 반응식
[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:20]([Cl:29])[CH:21]=[CH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1>C1(C)C(C)=CC=CC=1>[Cl-:29].[CH2:20]([P+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)[CH:21]=[CH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

참가 물질

4

반응물 2

HCID 11776TriphenylphosphineHCID 94242Benzene, (3-chloro-1-propenyl)-

생성물 1

HCID 73729[(E)-cinnamyl]-triphenyl-phosphonium chloride

시약·촉매·용매 1

HCID 7237O-Xylene용매

반응 조건

온도
130 °C

실험 절차

88.2 parts of triphenylphosphine was dissolved in 240 parts of xylene and 51.3 parts of cinnamyl chloride was added thereto. The mixture was heated at 130° C. for 4 hr. After the mixture was cooled to 30° C., the resulting colorless crystals were collected by filtration and washed with toluene to obtain 117.4 parts of cinnamyltriphenylphosphonium chloride (compound No. 15).

후처리

  1. additionwas added
  2. temperatureAfter the mixture was cooled to 30° C.
  3. filtrationthe resulting colorless crystals were collected by filtration
  4. washwashed with toluene

출처 및 근거

ORD 기록
ord-fa939c3d200942e0a4f0c4e26a59ee5a
출처 데이터셋
uspto-grants-1995_02
특허 번호
US05389486

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