4-Nitro-1,1'-biphenyl → 4-Nitrobiphenylsulfonic acid

HRID 29279

반응식

HRID 29279 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].Cl[S:17]([OH:20])(=[O:19])=[O:18]>C(Cl)(Cl)Cl>[N+:1]([C:4]1[CH:5]=[C:6]([S:17]([OH:20])(=[O:19])=[O:18])[C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH:9]=1)([O-:3])=[O:2]

참가 물질

4

반응물 2

HCID 71144-Nitro-1,1'-biphenylHCID 24638Chlorosulfonic acid

생성물 1

HCID 865990254-Nitrobiphenylsulfonic acid수율 61%

시약·촉매·용매 1

HCID 6212Chloroform용매

반응 조건

온도
60 °C

실험 절차

To a stirred solution of 4-nitrobiphenyl (50.00 g, 0.25 mol) in chloroform (750 mL) was added dropwise at room temperature chlorosulfonic acid (17 mL, 0.3 mol). The reaction mixture was stirred at 60° C. for 6 h. The white precipitate formed was collected by filtration and washed with cold chloroform. The product was air dried to give 31.00 g of 4-nitrobiphenylsulfonic acid (Yield 61%).

후처리

  1. customThe white precipitate formed
  2. filtrationwas collected by filtration
  3. washwashed with cold chloroform
  4. customdried

출처 및 근거

ORD 기록
ord-26444b97df234c98a762ba056033954a
출처 데이터셋
uspto-grants-2008_09
특허 번호
US07420001B2

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