Benzoyl Peroxide → Ethyl 3-bromo-4-(bromomethyl)benzoate
반응식
[Br:1][C:2]1[CH:3]=[C:4]([CH:10]=[CH:11][C:12]=1[CH3:13])[C:5]([O:7][CH2:8][CH3:9])=[O:6].C1C(=O)N([Br:21])C(=O)C1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:1][C:2]1[CH:3]=[C:4]([CH:10]=[CH:11][C:12]=1[CH2:13][Br:21])[C:5]([O:7][CH2:8][CH3:9])=[O:6]참가 물질
5
실험 절차
A mixture of 1.0 mmol of ethyl 3-bromo-4-methylbenzoate, 1.0 mmol NBS, and 0.02 mmol benzoyl peroxide in 5 mL CCl4 was refluxed for 4 h and then processed by filtration and chromatography to provide ethyl 3-bromo-4-bromomethylbenzoate as an oil.
후처리
- temperaturewas refluxed for 4 h
- filtrationprocessed by filtration and chromatography
출처 및 근거
- ORD 기록
- ord-43fc139c41d84237a967f7fa62214d1c
- 출처 데이터셋
- uspto-grants-1998_03
- 특허 번호
- US05731432
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