Triethylamine → HCID 58794783, 화합물

HRID 29730

반응식

HRID 29730 반응식
F[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=1.C1(C)[C:12]([NH2:19])=[C:13]([CH3:18])[C:14](N)=[CH:15][CH:16]=1.C([N:23]([CH2:26][CH3:27])[CH2:24][CH3:25])C>CS(C)=O>[N+:8]([C:5]1[CH:6]=[CH:7][C:2]([NH:19][CH2:12][C:13]2[CH:14]=[CH:15][CH:16]=[C:27]([CH2:26][NH:23][C:24]3[CH:25]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=3)[CH:18]=2)=[CH:3][CH:4]=1)([O-:10])=[O:9]

참가 물질

5

반응물 3

HCID 8471TriethylamineHCID 9590p-FluoronitrobenzeneHCID 46255812,4-Dimethylbenzene-1,3-diamine

생성물 1

HCID 58794783HCID 58794783, 화합물

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매

반응 조건

온도
60 °C

실험 절차

1.73 g of para-fluoronitrobenzene (2 eq.) were dissolved in 5 ml of DMSO. 1.2 equivalents of m-xylenediamine and 4 equivalents of triethylamine were added to the solution. The reaction mixture was heated at 60° C. for 20 hours. The mixture was then poured onto crushed ice and a precipitate formed. The latter was filtered, washed with water, and then dried.

후처리

  1. additionThe mixture was then poured
  2. customonto crushed ice
  3. customa precipitate formed
  4. filtrationThe latter was filtered
  5. washwashed with water
  6. customdried

출처 및 근거

ORD 기록
ord-e6dc97c099be42f593855bc0cd045bfe
출처 데이터셋
uspto-grants-2008_09
특허 번호
US07422609B2

연결된 노트

불러오는 중…