Diphenyl Ether → 1-Propanone, 1,1'-(oxydi-4,1-phenylene)bis-

HRID 325460노트

반응식

HRID 325460 반응식
[C:1]1([O:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:14](Cl)(=[O:17])[CH2:15][CH3:16].[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[C:14]([C:11]1[CH:10]=[CH:9][C:8]([O:7][C:1]2[CH:2]=[CH:3][C:4]([C:1](=[O:7])[CH2:2][CH3:3])=[CH:5][CH:6]=2)=[CH:13][CH:12]=1)(=[O:17])[CH2:15][CH3:16]

참가 물질

5

반응물 3

HCID 7583Diphenyl EtherHCID 62324Propionyl chlorideHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 106842951-Propanone, 1,1'-(oxydi-4,1-phenylene)bis-

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

Diphenyl ether (67 grams) was mixed with about 79 grams of propionyl chloride and 109 grams of aluminum chloride in about 150 ml of carbon disulfide. The product, 4-propionylphenyl ether, was isolated by hydrolysis of the mixture and conventional recrystallization techniques.

출처 및 근거

ORD 기록
ord-f15d0b40865b4e828bd2519484fc4805
출처 데이터셋
uspto-grants-1984_04
특허 번호
US04440943

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