1,1,3,3-Tetramethyl-disiloxane → 1,3-bis(N-cyclohexyl-3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

HRID 329699

반응식

HRID 329699 반응식
[CH2:1]([NH:4][CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1)[CH:2]=[CH2:3].[CH3:11][SiH:12]([CH3:17])[O:13][SiH:14]([CH3:16])[CH3:15]>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH:5]1([NH:4][CH2:1][CH2:2][CH2:3][Si:12]([CH3:17])([CH3:11])[O:13][Si:14]([CH2:3][CH2:2][CH2:1][NH:4][CH:5]2[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]2)([CH3:16])[CH3:15])[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1

참가 물질

4

반응물 2

HCID 186591,1,3,3-Tetramethyl-disiloxaneHCID 81115N-Allylcyclohexylamine

생성물 1

HCID 198714041,3-bis(N-cyclohexyl-3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

시약·촉매·용매 1

HCID 61859Chloroplatinic acid촉매

반응 조건

온도
110 °C

실험 절차

Following the technique described in Example 1, N-allylcyclohexylamine (0.173 mole), 1,1,3,3-tetramethyldisiloxane (0.0783 mole), and 0.05 g hexachloroplatinic acid are stirred at 70° C for eight hours at 110° C. under nitrogen. The product, in nearly quantitative yield, is purified by vacuum distillation at <1 torr at a temperature of 207°-210° C.

후처리

  1. distillationThe product, in nearly quantitative yield, is purified by vacuum distillation at <1 torr at a temperature of 207°-210° C.

출처 및 근거

ORD 기록
ord-c0289677df37416ba173f315dea44ca7
출처 데이터셋
uspto-grants-1990_01
특허 번호
US04892918

연결된 노트

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