Tetrafluoroboric acid → Diphenyliodonium Tetrafluoroborate

HRID 341872

반응식

HRID 341872 반응식
S(=O)(=O)(O)[O-].[C:6]1([I+:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[F:19][B-:20]([F:23])([F:22])[F:21].[H+].P(O)(O)O.[Cl-].C1([I+]C2C=CC=CC=2)C=CC=CC=1>O.F[B-](F)(F)F.[Ag+]>[F:19][B-:20]([F:23])([F:22])[F:21].[C:13]1([I+:12][C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

참가 물질

7

반응물 4

HCID 28118Tetrafluoroboric acidHCID 73870Diphenyliodonium chlorideHCID 107909Phosphorous acidHCID 170803Iodonium, diphenyl-, sulfate (1:1)

생성물 1

HCID 11122160Diphenyliodonium Tetrafluoroborate

시약·촉매·용매 2

HCID 159722Silver tetrafluoroborate촉매HCID 962Water용매

실험 절차

The aromatic iodonium complex salts may be prepared by metathesis of corresponding aromatic iodonium simple salts (such as, for example, the diphenyliodonium bisulfate) in accordance with the teachings of Beringer, et al., J. Am. Chem. Soc 81,342 (1959). Thus, for examples, the complex salt diphenyliodonium tetrafluoroborate is prepared by the addition at 60° C. of an aqueous solution containing 29.2 g (150 millimoles) silver fluoroborate, 2 g. fluoroboric acid, and 0.5 g phosphorous acid in about 30 ml of water to a solution of 44 g (139 millimoles) of diphenyliodonium chloride. The silver halide that precipitates is filtered off and the filtrate concentrated to yield diphenyliodonium fluoroborate which may be purified by recrystallization.

후처리

  1. customis prepared by the addition at 60° C. of an aqueous solution
  2. customThe silver halide that precipitates
  3. filtrationis filtered off
  4. concentrationthe filtrate concentrated

출처 및 근거

ORD 기록
ord-44f9ce577dfd4dff9a2a2ba86cf430a4
출처 데이터셋
uspto-grants-1999_01
특허 번호
US05856373

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