Hydrogen Peroxide → Adipate acetate

HRID 353006

반응식

HRID 353006 반응식
[OH-].[Na+].OO.[C:5]1(=[O:13])[O:12][C:10](=[O:11])[CH2:9][CH2:8][CH2:7][CH2:6]1.[C:14]([O:17]C(=O)C)(=[O:16])[CH3:15].S(=O)(=O)(O)O>O>[C:5]([O-:12])(=[O:13])[CH2:6][CH2:7][CH2:8][CH2:9][C:10]([O-:16])=[O:11].[C:14]([O-:17])(=[O:16])[CH3:15]

참가 물질

7

반응물 5

HCID 784Hydrogen PeroxideHCID 1118Sulfuric AcidHCID 7918Acetic Anhydride3회HCID 14798Sodium Hydroxide2회HCID 567658Adipic anhydride

생성물 1

HCID 18627148Adipate acetate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

The adipate/acetate of amylopectin potato starch was prepared using a 1:20 mixture. 810 gram dry starch was suspended in water to 39% suspension. The pH was adjusted to 8.5 with a 4.4% (w/w) sodium hydroxide solution and 1.3 ml of 30% of H2O2 solution were added. Then 6 g of 1:20 adipic anhydride reagent was added drop wise keeping the pH at 8.5 with a 4.4% (w/w) sodium hydroxide solution. Afterwards 41 grams of acetic anhydride was added drop wise to a pH 8.5. The acetic anhydride reaction was performed in approx. 1.5 hours. After the acetic anhydride dosage the suspension was stirred for 10 minutes at pH 8.5. Then the suspension was neutralised with sulphuric acid to pH 5.5 and the final product was dewatered, washed and dried using methods known to the art.

후처리

  1. additionwere added
  2. washwashed
  3. customdried

출처 및 근거

ORD 기록
ord-98ce9fa095b24ca291c483f835c38b0b
출처 데이터셋
uspto-grants-2004_06
특허 번호
US06749880B1

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