Sodium hydride → HCID 12961164, 화합물

HRID 355033

반응식

HRID 355033 반응식
[H-].[Na+].[N+:3]([C:6]1[CH:7]=[CH:8][C:9]2[O:13][C:12](=[O:14])[NH:11][C:10]=2[CH:15]=1)([O-:5])=[O:4].[CH3:16][O:17][C:18](=[O:27])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]Br>CN(C=O)C>[CH3:16][O:17][C:18](=[O:27])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][N:11]1[C:10]2[CH:15]=[C:6]([N+:3]([O-:5])=[O:4])[CH:7]=[CH:8][C:9]=2[O:13][C:12]1=[O:14]

참가 물질

5

반응물 3

HCID 24758Sodium hydrideHCID 2639655-Nitro-2,3-dihydro-1,3-benzoxazol-2-oneHCID 11107373Methyl 8-bromooctanoate

생성물 1

HCID 12961164HCID 12961164, 화합물

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

The product is produced as described in example 1 from 6 g. of NaH (80% suspension in mineral oil), 36 g. of 5-nitrobenzoxazolin-2-one (produced in usual manner by reacting 2-amino-4-nitrophenol-hydrochloride with phosgene), 400 cc. of DMF, 47.4 g. of 8-bromo caprylic acid methyl ester and 6 g. of NaJ.

후처리

  1. customThe product is produced

출처 및 근거

ORD 기록
ord-5083d77515734e688cceec493cc3548a
출처 데이터셋
uspto-grants-1983_03
특허 번호
US04377695

연결된 노트

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