Hydrochloric Acid → HCID 18940945, 화합물

HRID 356047

반응식

HRID 356047 반응식
C(N=[N+]=[N-])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[N:4][CH:3]=1.[N+:12]([C:15]1[CH:16]=[C:17]2[C:21](=[CH:22][CH:23]=1)[NH:20][CH2:19][CH2:18]2)([O-:14])=[O:13].[NH2:24][C:25](N)=[O:26].[ClH:28]>CCOCC>[ClH:28].[N+:12]([C:15]1[CH:16]=[C:17]2[C:21](=[CH:22][CH:23]=1)[N:20]([C:25](=[O:26])[NH:24][C:2]1[CH:3]=[N:4][CH:5]=[CH:6][CH:7]=1)[CH2:19][CH2:18]2)([O-:14])=[O:13]

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 1176UreaHCID 199143-Pyridinecarbonyl AzideHCID 362195-Nitroindoline

생성물 1

HCID 18940945HCID 18940945, 화합물수율 76%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

This material was prepared from nicotinoyl azide (0.43 g, 2.9 mmol) and 5-nitroindoline (0.38 g, 2.3 mmol), and conversion of the precipitated urea to the salt using excess HCl in ether, following the procedure of Example 2. This gave the title compound (0.64 g, 76%) as a light yellow powder, m.p. 244°-7° C. (dec.).

출처 및 근거

ORD 기록
ord-aafc92b2637a4682a1f40d81e42fab24
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05834494

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