홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Ethylbenzene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 358380
노트
인쇄 미리보기

반응식

HRID 358380 반응식
[CH2:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[CH3:2].C=CC1C=CC=CC=1.[C:17](#[N:20])[CH:18]=[CH2:19].C(OOC(C)(C)C)(C)(C)C>C(Cl)(Cl)Cl>[C:17](#[N:20])[CH:18]=[CH2:19].[CH2:2]=[CH:1][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 7500EthylbenzeneHCID 7501StyreneHCID 7855AcrylonitrileHCID 8033Di-tert-butyl peroxide

생성물 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

시약·촉매·용매 1

HCID 6212Chloroform용매

반응 조건

온도
60 °C

실험 절차

Fifty grams of PPO ([η]=0.49, chloroform, 25° C.), 50 g of ethylbenzene, 70 g of styrene, 30 g of acrylonitrile and 1.5 g of di-tertiary-butyl peroxide were charged into a 500 cc autoclave, and stirred at 60° C. to achieve uniform dissolution, after which the inside of the autoclave was displaced with nitrogen gas. The temperature of the reaction vessel was controlled to 140° C., and graft polymerization was effected for 2.5 hours. After completion of the reaction, the contents were withdrawn, and dissolved in 3500 ml of toluene by heating. Thereafter, methanol in an amount 10 times that of toluene was added thereto to obtain a resin powder. This powder was washed with methanol and then with methyl ethyl ketone as described in Example 1 to obtain a purified acrylonitrile-styrene grafted PPO. As the result of the organic elemental microanalysis, the degree of grafting was found 71% and the acrylonitrile content in this acrylonitrile-styrene copolymer graft side-chains was found to be 27%. Two grams of this acrylonitrile-styrene grafted PPO was dissolved in 40 ml of methylene chloride, placed in a stoppered Erlenmeyer flask, and allowed to stand in a constant temperature chamber at 23° C. Observation after 48 hours revealed that this solution was opaque. This solution was filtered to obtain a precipitate, which was dried and weighed to yield 1.26 g. In other words, 63% of the resin was recovered as the precipitate.

후처리

  1. dissolutiondissolution
  2. customwas controlled to 140° C.
  3. customgraft polymerization
  4. customAfter completion of the reaction
  5. customthe contents were withdrawn
  6. dissolutiondissolved in 3500 ml of toluene
  7. temperatureby heating
  8. additionThereafter, methanol in an amount 10 times that of toluene was added
  9. customto obtain a resin powder
  10. washThis powder was washed with methanol

출처 및 근거

ORD 기록
ord-4a8df058d6614b1495ead5169d0323b5
출처 데이터셋
uspto-grants-1984_08
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04467076

반응 노트

불러오는 중…

이 페이지에서참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트