Water → (2,6-Dimethyl-3-nitrophenyl)methanol

HRID 365559

반응식

HRID 365559 반응식
C([O:4][CH2:5][C:6]1[C:11]([CH3:12])=[CH:10][CH:9]=[C:8]([N+:13]([O-:15])=[O:14])[C:7]=1[CH3:16])(=O)C.[OH-].[Na+].O>CO>[CH3:16][C:7]1[C:8]([N+:13]([O-:15])=[O:14])=[CH:9][CH:10]=[C:11]([CH3:12])[C:6]=1[CH2:5][OH:4]

참가 물질

5

반응물 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 10537042(2,6-Dimethyl-3-nitrophenyl)methyl acetate

생성물 1

HCID 10487641(2,6-Dimethyl-3-nitrophenyl)methanol수율 82.4%

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

To a solution of 2,6-dimethyl-3-nitrobenzyl acetate (26.9 g) in methanol (266 ml) was added aqueous 1N sodium hydroxide solution (133 ml) at ambient temperature for 30 minutes. To the mixture was added water, and the precipitate was collected by filtration to give 2,6-dimethyl-3-nitrobenzyl alcohol (18.0 g) as pale yellow crystals.

후처리

  1. filtrationthe precipitate was collected by filtration

출처 및 근거

ORD 기록
ord-f1fb1725b3bb469d9f57f73a62124038
출처 데이터셋
uspto-grants-2000_10
특허 번호
US06127389

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