Hexylbenzene → 4'-n-Hexylbenzoin

HRID 375044

반응식

HRID 375044 반응식
O.[C:2]1([C:8]([CH:10]=[O:11])=[O:9])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:12]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]>ClC(Cl)C.[Ti](Cl)(Cl)(Cl)Cl>[CH2:12]([C:18]1[CH:19]=[CH:20][C:21]([CH:10]([OH:11])[C:8](=[O:9])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[CH:22][CH:23]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

참가 물질

5

반응물 2

HCID 14109HexylbenzeneHCID 12215922Glyoxal, phenyl-, hydrate

생성물 1

HCID 235130694'-n-Hexylbenzoin

시약·촉매·용매 2

HCID 24193Titanium Tetrachloride촉매HCID 63651,1-Dichloroethane용매

실험 절차

Phenylglyoxal monohydrate (304 mg, 2 mM) and n-hexylbenzene (0.76 ml, 4 mM) were dissolved in dichloroethane (3 ml), titanium tetrachloride (0.33 ml, 3 mM) was added, and reacted at room temperature for 1 hour. Using the same procedure as in Example 1, 4'-n-hexylbenzoin was obtained as crystal (352.8 mg, 59.4% yield).

후처리

  1. customreacted at room temperature for 1 hour

출처 및 근거

ORD 기록
ord-d0629f092da5423c9442b00eb2dd7720
출처 데이터셋
uspto-grants-1996_01
특허 번호
US05484689

연결된 노트

불러오는 중…