Sodium Hydroxide → Oleylamine

HRID 381806

반응식

HRID 381806 반응식
[C:1](#[N:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH-].[Na+]>O>[CH2:1]([NH2:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

참가 물질

4

반응물 2

HCID 14798Sodium HydroxideHCID 6420241(Z)-9-Octadecenenitrile

생성물 1

HCID 5356789Oleylamine수율 94%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

300 g of oleonitrile were fed into a 1 liter autoclave and 2 g of Catalyst A, 6 g of water and 0.5 g of 48% sodium hydroxide were put thereinto. After purging with nitrogen gas, the reaction was carried out under the hydrogen pressure of 1.0 MpaG at the reaction temperature of 130° C. The reaction-finishing point was determined at the point where the hydrogen gas was no longer absorbed. The reaction system was aged further for 15 minutes. Absorption of hydrogen gas proceeded smoothly and the absorption was completed in 1.3 hour. After finish of the reaction and aging, the reaction product was taken out from the reactor and the catalyst was removed off. Then, the reaction product was distilled and purified under 0.27 kPa at 220° C. Oleylamine was obtained with yield of 94%.

후처리

  1. customAfter purging with nitrogen gas
  2. customwas carried out under the hydrogen pressure of 1.0 MpaG at the reaction temperature of 130° C
  3. customno longer absorbed
  4. customAbsorption of hydrogen gas
  5. customthe absorption
  6. waitwas completed in 1.3 hour
  7. customAfter finish of the reaction
  8. customthe catalyst was removed off
  9. distillationThen, the reaction product was distilled
  10. custompurified under 0.27 kPa at 220° C

출처 및 근거

ORD 기록
ord-16a236bf04b84b9e815c4382b755a4ee
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06307104B1

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