Benzyl Benzoate → Sodium Benzoate

HRID 3937

반응식

HRID 3937 반응식
[C:1]([O:9]CC1C=CC=CC=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C[Si](C)(C)[O-].[Na+:22]>O1CCCC1>[C:1]([O-:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Na+:22]

참가 물질

4

반응물 2

HCID 2345Benzyl BenzoateHCID 23672319Sodium trimethylsilanolate

생성물 1

HCID 517055Sodium Benzoate수율 322%

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

The procedure of Example 1 was followed using benzyl benzoate (4.8 mL, 5 mmol), sodium trimethylsilanolate (2.82 g, 25 mmol), dry tetrahydrofuran (100 mL), and 6.25 h of heating at reflux. The reaction mixture was cooled to room temperature and sodium benzoate (2.32 g, 64% yield) was isolated as a white solid: 1H NMR (D2O) δ 7.0-8.0 ppm (m, Ar--H's, 5H). Anal. Calcd. for C7H5NaO: C, 58.34; H, 3.50; Na, 15.95. Found: C, 57.99, 57.94; H, 3.80, 3.83; Na, 16.38, 16.60.

후처리

  1. temperatureof heating
  2. temperatureat reflux

출처 및 근거

ORD 기록
ord-a68a06a0effb494f98d875d04106fb3e
출처 데이터셋
uspto-grants-1988_02
특허 번호
US04723016

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