Sodium Hydroxide → Quinacridone

HRID 399178

반응식

HRID 399178 반응식
[OH-].[Na+].[CH2:3]1[C:8]2[NH:9][C:10]3[C:15]([C:16](=[O:17])[C:7]=2[CH2:6][C:5]2[NH:18][C:19]4[C:24]([C:25](=[O:26])[C:4]1=2)=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:14][CH:13]=[CH:12][CH:11]=3.[N+](C1C=C(S([O-])(=O)=O)C=CC=1)([O-])=O.[Na+]>CO>[CH:22]1[CH:23]=[C:24]2[C:25]([C:4]3[C:5]([NH:18][C:19]2=[CH:20][CH:21]=1)=[CH:6][C:7]1[C:16]([C:15]2[C:10]([NH:9][C:8]=1[CH:3]=3)=[CH:11][CH:12]=[CH:13][CH:14]=2)=[O:17])=[O:26]

참가 물질

5

반응물 3

HCID 14798Sodium HydroxideHCID 31389Sodium 3-nitrobenzenesulfonateHCID 79973Quino(2,3-b)acridine-7,14-dione, 5,6,12,13-tetrahydro-

생성물 1

HCID 13976Quinacridone

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

79 Parts of methanol and 12 parts of a 50% NaOH aqeuous solution were fully stirred in a flask of stainless steel. 10 Parts of the 6,13-dihydroquinacridone obtained in Example 9 and 10 parts of sodium m-nitrobenzenesulfonate were gradually added, and the mixture was refluxed at 70° to 75° C. for 3 to 5 hours. The mixture was cooled until it had a temperature of 40° C. or lower, and the mixture was filtered. The resultant cake was washed with hot water until the wash water was colorless and transparent, and dried, to give 9.78 parts (98.4% of the theoretical yield) of an unsubstituted quinacridone. The quinacridone was measured for a purity by IR and absorbance to show 99.2% of quinacridone and 0.8% of 6,13-dihydroquinacridone. The quinacridone had a specific surface area of 22.8 m2 /g.

후처리

  1. temperaturethe mixture was refluxed at 70° to 75° C. for 3 to 5 hours
  2. temperatureThe mixture was cooled until it
  3. customa temperature of 40° C.
  4. filtrationlower, and the mixture was filtered
  5. washThe resultant cake was washed with hot water until the wash water
  6. customtransparent, and dried
  7. customto give 9.78 parts (98.4% of the

출처 및 근거

ORD 기록
ord-e943fda8c8104ec9adbfc0caeaa13b9e
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05817817

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