Hydrochloric Acid → 1,2,4,5-Benzenetetrol
반응식
[OH:1][C:2]1[C:3](=[O:10])[CH:4]=[C:5]([OH:9])[C:6](=[O:8])[CH:7]=1.[O-]S(S([O-])=O)=O.[Na+].[Na+].Cl>O>[OH:1][C:2]1[CH:7]=[C:6]([OH:8])[C:5]([OH:9])=[CH:4][C:3]=1[OH:10]참가 물질
5
실험 절차
2,5-Dihydroxy-1,4-benzoquinone (4.00 g, 28.55 mmol) was suspended in water (50 ml, distilled) followed by Na2S2O4 (10.00 g, 57.47 mmol) and HCl (5.5 g, 55.75 mmol conc. soln.). The mixture was stirred 30 min. at room temperature and evaporated to dryness. The residue was washed with THF (40 ml) and filtered. The THF was evaporated yielding 2.00 g (14.07 mmol, 49.3%) of the title substance.
후처리
- customevaporated to dryness
- washThe residue was washed with THF (40 ml)
- filtrationfiltered
- customThe THF was evaporated
- customyielding 2.00 g (14.07 mmol, 49.3%) of the title substance
출처 및 근거
- ORD 기록
- ord-150c9cd783ea4d13966ca91feada9b65
- 출처 데이터셋
- uspto-grants-1998_10
- 특허 번호
- US05827501
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