Carbon Dioxide → delta-Gluconolactone

HRID 411798

반응식

C(=O)([O-])[O-].[Ba+2].C(=O)=O.BrBr.[O:11]=[CH:12][C@@H:13]([C@H:15]([C@@H:17]([C@@H:19]([CH2:21][OH:22])[OH:20])[OH:18])[OH:16])[OH:14]>>[CH2:21]([OH:22])[C@H:19]1[O:20][C:12](=[O:11])[C@H:13]([OH:14])[C@@H:15]([OH:16])[C@@H:17]1[OH:18]

참가 물질

반응물 4

HCID 280Carbon Dioxide

HCID 10563Barium Carbonate

HCID 24408Bromine

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 7027delta-Gluconolactone

반응 조건

온도: 25 °C

실험 절차

7,500 parts by mass of a 12% aqueous solution of barium carbonate were saturated with carbon dioxide, and 300 parts by mass of bromine and 280 parts by mass of the glucose were added and agitated for 30 minutes at 25° C. to obtain 230 parts by mass of gluconolactone.

후처리

additionwere added

출처 및 근거

ORD 기록: ord-bff5f2f369f94108b98d65cdcca3c349
출처 데이터셋: uspto-grants-2003_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06559275B2

연결된 노트

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