Carbon Dioxide → delta-Gluconolactone

HRID 411803

반응식

C(=O)([O-])[O-].[Ba+2].C(=O)=O.BrBr.[O:11]=[CH:12][C@@H:13]([C@H:15]([C@@H:17]([C@@H:19]([CH2:21][OH:22])[OH:20])[OH:18])[OH:16])[OH:14]>>[CH2:21]([OH:22])[C@H:19]1[O:20][C:12](=[O:11])[C@H:13]([OH:14])[C@@H:15]([OH:16])[C@@H:17]1[OH:18]

참가 물질

반응물 4

HCID 280Carbon Dioxide

HCID 10563Barium Carbonate

HCID 24408Bromine

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 7027delta-Gluconolactone

반응 조건

온도: 25 °C

실험 절차

Then, 8,000 parts by mass of a 12% aqueous solution of barium carbonate were saturated with carbon dioxide, and 330 parts by mass of bromine and 300 parts by mass of the glucose obtained above were added and agitated for 30 minutes at 25° C. to obtain 250 parts by mass of gluconolactone represented by the following chemical formula (III):

후처리

customobtained
additionabove were added

출처 및 근거

ORD 기록: ord-2425b342699c449a8922894b7744ce71
출처 데이터셋: uspto-grants-2003_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06559275B2

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