Carbon Dioxide → delta-Gluconolactone

HRID 411806노트

반응식

C(=O)([O-])[O-].[Ba+2].C(=O)=O.BrBr.[O:11]=[CH:12][C@@H:13]([C@H:15]([C@@H:17]([C@@H:19]([CH2:21][OH:22])[OH:20])[OH:18])[OH:16])[OH:14]>>[CH2:21]([OH:22])[C@H:19]1[O:20][C:12](=[O:11])[C@H:13]([OH:14])[C@@H:15]([OH:16])[C@@H:17]1[OH:18]

참가 물질

반응물 4

HCID 280Carbon Dioxide

HCID 10563Barium Carbonate

HCID 24408Bromine

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 7027delta-Gluconolactone

반응 조건

온도: 25 °C

실험 절차

7,500 parts by mass of a 12% aqueous solution of barium carbonate were saturated with carbon dioxide, and 300 parts by mass of bromine and 280 parts by mass of the obtained glucose were added and agitated for 30 minutes at 25° C. to obtain 230 parts by mass of gluconolactone.

후처리

additionwere added

출처 및 근거

ORD 기록: ord-f6b8388b62a044f0b756b6fec62fcd44
출처 데이터셋: uspto-grants-2003_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06559275B2

반응 노트

불러오는 중…