p-n-Octadecyloxybenzoic acid → 4-(trans-3-Decenyloxy)-benzoic acid

HRID 413635

반응식

HRID 413635 반응식
C[O:2][C:3](=[O:21])[C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH:6][CH:5]=1.O.[OH-].[Li+].C(OC1C=CC(C(O)=O)=CC=1)CCCCCCCCCCCCCCCCC>CO>[CH2:11]([O:10][C:7]1[CH:6]=[CH:5][C:4]([C:3]([OH:21])=[O:2])=[CH:9][CH:8]=1)[CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

참가 물질

5

반응물 3

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrateHCID 18521096Methyl-4-(trans-3-decenyloxy)-benzoate

생성물 1

HCID 185211034-(trans-3-Decenyloxy)-benzoic acid

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

Ester 35h (600 mg, 2.07 mmol), and lithium hydroxide monohydrate (867 mg, 20.7 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 500 mg (87%) of a white powder which was not quite pure (95%). The product was used without further purification.

후처리

  1. customThe product was used without further purification

출처 및 근거

ORD 기록
ord-d8c3667c163749e7a921df5f12e71ed3
출처 데이터셋
uspto-grants-2003_05
특허 번호
US06569504B1

연결된 노트

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