Hydrochloric Acid → 3-Chloroanthracen-9(10h)-one

HRID 414473

반응식

HRID 414473 반응식
[Sn].[Cl:2][C:3]1[CH:16]=[CH:15][C:14]2[C:13](=[O:17])[C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6](=[O:18])[C:5]=2[CH:4]=1.Cl>C(O)(=O)C>[Cl:2][C:3]1[CH:16]=[CH:15][C:14]2[CH2:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6](=[O:18])[C:5]=2[CH:4]=1.[Cl:2][C:3]1[CH:16]=[CH:15][C:14]2[C:13](=[O:17])[C:12]3[C:7]([CH2:6][C:5]=2[CH:4]=1)=[CH:8][CH:9]=[CH:10][CH:11]=3

참가 물질

6

반응물 3

HCID 313Hydrochloric AcidHCID 85532-ChloroanthraquinoneHCID 5352426Tin atom

생성물 2

HCID 786013-Chloroanthracen-9(10h)-oneHCID 130135132-Chloroanthrone

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Tin powder (100 g) and 2-chloroanthraquinone (70 g) were refluxed in acetic acid (500 ml) while concentrated hydrochloric acid (130 ml) was added over a period of 3 hours. The solution was cooled and the product was separated by filtration, and then chromatographed on silica gel, eluting with benzene:ether, so as to afford 2-chloroanthrone and 3-chloroanthrone.

후처리

  1. additionwas added over a period of 3 hours
  2. temperatureThe solution was cooled
  3. customthe product was separated by filtration
  4. customchromatographed on silica gel
  5. washeluting with benzene

출처 및 근거

ORD 기록
ord-69046feb53fc41adb7568e4b0908623c
출처 데이터셋
uspto-grants-1988_12
특허 번호
US04792551

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