Allyl bromide → Diethyl allylphosphonate

HRID 417170

반응식

HRID 417170 반응식
[CH2:1](Br)[CH:2]=[CH2:3].[P:5]([O:12]CC)([O:9][CH2:10][CH3:11])[O:6][CH2:7][CH3:8]>C(Cl)(Cl)Cl>[CH2:1]([P:5](=[O:12])([O:9][CH2:10][CH3:11])[O:6][CH2:7][CH3:8])[CH:2]=[CH2:3]

참가 물질

4

반응물 2

HCID 7841Allyl bromideHCID 31215Triethyl phosphite

생성물 1

HCID 573014Diethyl allylphosphonate

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

Allyl bromide (3.6 g, 30.09 mmol) and triethyl phosphite (1 g, 6 mmol) were dissolved and reacted in chloroform (30 mL). Then, the resulting reaction solution was refluxed for 12 hours, cooled to room temperature and filtered through a glass filter. Chloroform was completely removed from the solution under vacuum to thereby give an oily compound as the title compound. The 1H NMR and 13CNMR results of the compound thus obtained are given as follows.

후처리

  1. customThen, the resulting reaction solution
  2. temperaturewas refluxed for 12 hours
  3. filtrationfiltered through a glass
  4. filtrationfilter
  5. customChloroform was completely removed from the solution under vacuum

출처 및 근거

ORD 기록
ord-b5d43975c1e94e3580ccaef9602c533d
출처 데이터셋
uspto-grants-2012_01
특허 번호
US08089682B2

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