Chloroform → CCl3CF2CHFCF3

HRID 41731

반응식

HRID 41731 반응식
[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[CH:10]([Cl:13])([Cl:12])[Cl:11]>>[C:10]([C:4]([CH:3]([C:2]([F:9])([F:8])[F:1])[F:7])([F:6])[F:5])([Cl:13])([Cl:12])[Cl:11]

참가 물질

3

반응물 2

HCID 6212ChloroformHCID 8302Hexafluoropropylene

생성물 1

HCID 12829385CCl3CF2CHFCF3

반응 조건

온도
290 °C

실험 절차

A 0.5 inch (12.7 mm) by 40 inch (101.6 cm) plug flow reactor that is packed with Helipack Monel support is heated to 290° C. A 50/50 (molar %) mixture of hexafluoropropene and chloroform is fed into the reactor at about 1.5 g/min. The reactor pressure is maintained at 100 psig. The effluent from the reactor is fed into a distillation column and the unreacted reagents removed by distillation and recycled. The product CCl3CF2CHFCF3 is used in the next reaction.

후처리

  1. temperatureThe reactor pressure is maintained at 100 psig
  2. distillationThe effluent from the reactor is fed into a distillation column
  3. customthe unreacted reagents removed by distillation
  4. customThe product CCl3CF2CHFCF3 is used in the next reaction

출처 및 근거

ORD 기록
ord-e25e851eb2fd41f9bfbe6fa77cb92408
출처 데이터셋
uspto-grants-2013_09
특허 번호
US08530709B2

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