Chloroform → CCl3CF2CHFCF3

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[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[CH:10]([Cl:13])([Cl:12])[Cl:11]>>[C:10]([C:4]([CH:3]([C:2]([F:9])([F:8])[F:1])[F:7])([F:6])[F:5])([Cl:13])([Cl:12])[Cl:11]

참가 물질

반응물 2

HCID 6212Chloroform

HCID 8302Hexafluoropropylene

생성물 1

HCID 12829385CCl3CF2CHFCF3

반응 조건

온도: 290 °C

실험 절차

A 0.5 inch (12.7 mm) by 40 inch (101.6 cm) plug flow reactor that is packed with Helipack Monel support is heated to 290° C. A 50/50 (molar %) mixture of hexafluoropropene and chloroform is fed into the reactor at about 1.5 g/min. The reactor pressure is maintained at 100 psig. The effluent from the reactor is fed into a distillation column and the unreacted reagents removed by distillation and recycled. The product CCl3CF2CHFCF3 is used in the next reaction.

후처리

temperatureThe reactor pressure is maintained at 100 psig
distillationThe effluent from the reactor is fed into a distillation column
customthe unreacted reagents removed by distillation
customThe product CCl3CF2CHFCF3 is used in the next reaction

출처 및 근거

ORD 기록: ord-e25e851eb2fd41f9bfbe6fa77cb92408
출처 데이터셋: uspto-grants-2013_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08530709B2

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