Nitrate → HCID 59627748, 화합물

반응식

C[O:2][C:3]([C:5]1[CH:6]=[C:7]([C:12]2[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][CH:13]=2)[CH:8]=[C:9](N)[CH:10]=1)=[O:4].C(I)[I:20].[N+]([O-])([O-])=O>>[I:20][C:9]1[CH:10]=[C:5]([C:3]([OH:2])=[O:4])[CH:6]=[C:7]([C:12]2[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][CH:13]=2)[CH:8]=1

참가 물질

반응물 3

HCID 943Nitrate

HCID 6346Diiodomethane

HCID 57850917Methyl 5-amino-4'-methylbiphenyl-3-carboxylate

생성물 1

HCID 59627748HCID 59627748, 화합물

실험 절차

5-Amino-4′-methyl-biphenyl-3-carboxylic acid methyl ester was treated with methylene iodide and isoamy nitrate using the procedure of step 5 of preparation 5, to afford 5-iodo-4′-methyl-biphenyl-3-carboxylic acid, MS (M+H)=353.

후처리

customthe procedure of step 5 of preparation 5

출처 및 근거

ORD 기록: ord-e69d4cc5df09407e9f8168b1c9d6a281
출처 데이터셋: uspto-grants-2012_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08093275B2

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