Sodium Hydroxide → 4,4'-Bis(hydroxymethyl)biphenyl

HRID 427045

반응식

HRID 427045 반응식
C([O:4][CH2:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[CH:17]=[CH:16][C:15]([CH2:18][O:19]C(=O)C)=[CH:14][CH:13]=2)=[CH:8][CH:7]=1)(=O)C.[OH-].[Na+]>C(O)C>[OH:4][CH2:5][C:6]1[CH:7]=[CH:8][C:9]([C:12]2[CH:17]=[CH:16][C:15]([CH2:18][OH:19])=[CH:14][CH:13]=2)=[CH:10][CH:11]=1

참가 물질

4

반응물 2

HCID 14798Sodium HydroxideHCID 113355074,4'-Bis(acetoxymethyl)biphenyl

생성물 1

HCID 6117864,4'-Bis(hydroxymethyl)biphenyl수율 80%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

0.1 moles 4,4'bis(acetoxymethyl)biphenyl (prepared by method C above), 0.4 mole sodium hydroxide as 23 percent aqueous solution and 50 mls ethanol were refluxed for 3 hours with stirring. The reaction mixture was filtered and the precipitate washed with water and dried to yield 0.08 moles product=80 percent of theory. m.p. 195°-97° C.

후처리

  1. filtrationThe reaction mixture was filtered
  2. washthe precipitate washed with water
  3. customdried

출처 및 근거

ORD 기록
ord-e0db6938a15b46bc973c1327f6ad7f43
출처 데이터셋
uspto-grants-1979_10
특허 번호
US04172858

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