Phthalic Anhydride → N-Hydroxyphthalimide
반응식
[C:1]1(=O)[O:6][C:4](=[O:5])[C:3]2=[CH:7][CH:8]=[CH:9][CH:10]=[C:2]12.P([O-])([O-])([O-])=O.[OH:17][NH3+:18].O[NH3+].O[NH3+]>O>[OH:17][N:18]1[C:4](=[O:5])[C:3]2=[CH:7][CH:8]=[CH:9][CH:10]=[C:2]2[C:1]1=[O:6]참가 물질
4
반응 조건
- 온도
- 130 °C
실험 절차
1.48 g (10.0 mmol) of phthalic anhydride and 0.723 g (3.67 mmol) of hydroxylammonium phosphate were pulverized, mixed and, following the addition of 2 ml of water, heated at a bath temperature of 130° C. for about 1½ hours. The cooled lemon-yellow reaction mixture was diluted with water, and the solid was filtered off with suction, washed with water and dried at 50° C. The yield was 1.39 g (86%).
후처리
- additionmixed
- filtrationthe solid was filtered off with suction
- washwashed with water
- customdried at 50° C
출처 및 근거
- ORD 기록
- ord-ffb4abcd931e499bb3815317beb34444
- 출처 데이터셋
- uspto-grants-2001_11
- 특허 번호
- US06316639B1
반응 노트
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