Sodium Hydroxide → HCID 20452227, 화합물

HRID 435222

반응식

HRID 435222 반응식
[NH:1]([CH:19]1[CH2:24][C:23]([CH3:26])([CH3:25])[NH:22][C:21]([CH3:28])([CH3:27])[CH2:20]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]1.[CH2:29]([O:32][C:33]1[N:38]=[C:37](Cl)[N:36]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:43])[CH3:42])[N:34]=1)[CH:30]=[CH2:31].[OH-:49].[Na+]>C1(C)C(C)=CC=CC=1>[CH3:25][C:23]1([CH3:26])[CH2:24][CH:19]([N:1]([C:37]2[N:38]=[C:33]([O:49][CH2:31][CH:30]=[CH2:29])[N:34]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:46])([CH3:48])[CH3:47])([CH3:43])[CH3:42])[N:36]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][N:8]([C:37]2[N:38]=[C:33]([O:32][CH2:29][CH:30]=[CH2:31])[N:34]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:43])[CH3:42])[N:36]=2)[CH:9]2[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:17])([CH3:18])[CH2:10]2)[CH2:20][C:21]([CH3:28])([CH3:27])[NH:22]1

참가 물질

5

반응물 3

HCID 14798Sodium HydroxideHCID 934191,6-Bis(2,2,6,6-tetramethyl-4-piperidylamino)hexaneHCID 20452243HCID 20452243, 화합물

생성물 1

HCID 20452227HCID 20452227, 화합물수율 68.3%

시약·촉매·용매 1

HCID 7237O-Xylene용매

실험 절차

A stirred mixture of 4,4'(hexamethylenediimino)bis(2,2,6,6-tetramethylpiperidine) (10.0 grams; 0.025 mole), 2-allyloxy-4-chloro-6-t-octylamino-1,3,5-triazine (15.1 grams; 0.05 mole), and powdered sodium hydroxide (2.0 grams; 0.05 mole) in xylene (150 mls) is heated at reflux for 24 hours while removing by-product water by means of a trap. The reaction mixture is filtered while hot to remove insolubles. Upon cooling the filtrate, a white crystalline solid precipitates. The solid is recovered by filtration and dried to obtain 15.7 grams of the desired product, mp 210°-212° C.

후처리

  1. temperatureis heated
  2. temperatureat reflux for 24 hours
  3. customwhile removing by-product water by means of a trap
  4. filtrationThe reaction mixture is filtered while hot
  5. customto remove insolubles
  6. temperatureUpon cooling the filtrate
  7. customa white crystalline solid precipitates
  8. filtrationThe solid is recovered by filtration
  9. customdried

출처 및 근거

ORD 기록
ord-00f27744898545709f42e3e11a37d0a1
출처 데이터셋
uspto-grants-1983_08
특허 번호
US04400505

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