Benzyl Chloride → Benzene, 1,1'-[selenobis(methylene)]bis-

HRID 436711

반응식

HRID 436711 반응식
[Se].[BH4-].[Na+].[SeH2:4].[Na].[CH2:6](Cl)[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[CH2:6]([Se:4][CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

참가 물질

5

반응물 4

HCID 7503Benzyl ChlorideHCID 4311764Sodium borohydrideHCID 6326970SeleniumHCID 131710529CID 131710529

생성물 1

HCID 98827Benzene, 1,1'-[selenobis(methylene)]bis-

실험 절차

Into a 250 milliliter 3 necked round bottom flask equipped with an addition funnel and a magnetic stirring bar is placed 4.6 grams (0.058 moles) of selenium powder and 50 milliliters of deoxygenated distilled water. The flask is purged of air with nitrogen and a solution comprising 4.6 grams (0.122 moles) sodium borohydride in 50 milliliters of deoxygenated distilled water slowly added to the solution in the flask from the addition funnel. Upon contacting of these two solutions, vigorous hydrogen evolution occurs and the selenium powder is consumed thereby yielding a solution containing sodium hydrogen selenide. About 14.6 grams (0.166 moles) benzylchloride is now introduced into the flask and the resulting mixture stirred at room temperature for 18 hours. The solid product thus produced is collected by filtration washed with water and recrystallized twice from pentane. Yield 11.81 grams of rod like crystals, (m.p. 45° to 46° C.).

후처리

  1. customof deoxygenated
  2. distillationdistilled water
  3. customThe flask is purged of air with nitrogen
  4. customof deoxygenated
  5. distillationdistilled water
  6. additionslowly added to the solution in the flask from the addition funnel
  7. customthe selenium powder is consumed
  8. customthereby yielding a solution
  9. customThe solid product thus produced
  10. filtrationis collected by filtration
  11. washwashed with water
  12. customrecrystallized twice from pentane

출처 및 근거

ORD 기록
ord-ae27ed5741be498f8069185c5a8cb9f2
출처 데이터셋
uspto-grants-1977_06
특허 번호
US04028203

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