Hydrochloric Acid → 1-Triethoxysilylglycerol

HRID 442812

반응식

Cl[Si:2]([O:9][CH2:10][CH3:11])([O:6][CH2:7][CH3:8])[O:3][CH2:4][CH3:5].C1(NC2CCCCC2)CCCCC1.Cl[SiH3].Cl.[OH:28][CH2:29][CH:30]([CH2:32][OH:33])[OH:31]>>[CH2:4]([O:3][Si:2]([O:9][CH2:10][CH3:11])([O:6][CH2:7][CH3:8])[O:28][CH2:29][CH:30]([CH2:32][OH:33])[OH:31])[CH3:5]

참가 물질

반응물 5

HCID 313Hydrochloric Acid

HCID 753Glycerol

HCID 7582Dicyclohexylamine

HCID 61622Chlorosilane

HCID 78398Triethoxychlorosilane

생성물 1

HCID 544271121-Triethoxysilylglycerol수율 90%

실험 절차

Glycerol (GL) was reacted with chlorotriethoxysilane (CTS) in a 1:1 ratio at 0° C. in a 50/50 mixture of ethanol/cyclomethicone, using a 1:1 ratio of dicyclohexylamine to chlorosilane as the HCl scavenger. The resulting product, 1-triethoxysilylglycerol, was obtained in 90% yield and was dissolved to a 10% by weight solution in a 50/50 by volume mixture of ethanol/cyclomethicone.

출처 및 근거

ORD 기록: ord-34a137cec1d84963b67a4990cd97ac55
출처 데이터셋: uspto-grants-1999_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05891914

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