Phenyl phenylglyoxylate → Phenyl benzoate

HRID 443085

반응식

HRID 443085 반응식
[C:1]1([C:7](=O)[C:8]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3]C=1>[Cl-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)Cl>[C:8]([O:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)(=[O:9])[C:7]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:1]=1

참가 물질

4

반응물 1

HCID 13975017Phenyl phenylglyoxylate

생성물 1

HCID 7169Phenyl benzoate

시약·촉매·용매 2

HCID 164911Tetraphenylphosphonium Chloride촉매HCID 6212Chloroform용매

실험 절차

The decarbonylation reaction of phenyl phenylglyoxylate (PPG) was repeated in the manner as described in Example 79, except that neither tetraphenylphosphonium chloride nor chloroform was employed. The results are also set forth in Table 12.

출처 및 근거

ORD 기록
ord-9fbbfbfddd16461f95e28fccac4f61d6
출처 데이터셋
uspto-grants-1999_04
특허 번호
US05892091

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