테트라페닐 인 클로라이드

Tetraphenylphosphonium Chloride

HCID 164911CAS 2001-45-8

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: [Cl-].c1ccc([P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1
InChIKey: WAGFXJQAIZNSEQ-UHFFFAOYSA-M
분자식: C24H20ClP
평균 분자량: 374.8 g/mol
단동위원소 질량: 374.09911495

이름 및 식별자

우선 이름: Tetraphenylphosphonium Chloride
IUPAC: tetraphenylphosphanium chloride
현지명: 테트라페닐 인 클로라이드
영어명: Tetraphenylphosphonium chloride
분자식: C24H20ClP
분자량: 374.84

이름 및 동의어

Tetraphenylphosphonium chloride2001-45-8DTXSID00897533RefChem:188844DTXCID401326887217-890-3Phosphonium, tetraphenyl-, chlorideC24H20ClPPhosphonium, tetraphenyl-, chloride (1:1)MFCD00011916tetraphenylphosphanium;chloridePh4PCl

이름 더 보기

테트라페닐포스포늄클로라이드테트라페닐인클로라이드테트라페닐포스포늄 클로라이드Tetraphenyl phosphonTetraphenylchlorophosphineTETRAPHENYLPHOSPONIUM CHLORIDETETRAPHENYLPHOSPHONIUM CHLORIDetraphenylphosphanium,chlorideTetraphenylphosphanium chlorideTetraphenylphosphonium chloride,98%Tetraphenylphosphonium chloride, 98.5%

EINECS 217-890-3SCHEMBL126056SY032650Q7706653Tetraphenylphosphonium chloride, for the spectrophotometric det. of Bi, Co, >=97.0%Tetraphenylphosphoniumchloridetetraphenylphophonium chlorideTetraphenylphosphonium chloride, 98%

데이터베이스 식별자

CAS: 2001-45-8
PubChem CID: 164911
DTXSID: DTXSID00897533
ChEMBL: CHEMBL223885
EC Number: 217-890-3

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 4
무거운 원자 수: 26
형식 전하: 0
복잡도: 301

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Phosphorus Compounds

Physical DescriptionWhite to off-white hygroscopic powder; [Acros Organics MSDS]

물리화학적 성질

녹는점: 272 · 272-274 °C(lit.)
저장 조건: Inert atmosphere,Room Temperature
물리적 상태: 결정성 분말
색상: 흰색에서 베이지색
수용성: 물에 용해됩니다.
BRN: 3922393 · 3922393
InChI: InChI=1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
InChIKey: WAGFXJQAIZNSEQ-UHFFFAOYSA-M
SMILES: [P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[Cl-]

화학적 성질

White to beige crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (97.9%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationPhosphonium, tetraphenyl-, chloride: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryAn irritant; [Acros Organics MSDS] See Tetraphenylphosphonium. See Benzyltriphenylphosphonium chloride.

Hazard Classes and CategoriesSkin Irrit. 2 (97.9%)

안전 데이터

wgk: 3
HS 번호: 29310095
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
F 고인화성물질: 3-10
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

약리 정보

MeSH Pharmacological Classification · 2건

Substances that inhibit or prevent the proliferation of NEOPLASMS.

Substances used for the detection, identification, analysis, etc. of chemical, biological, or pathologic processes or conditions. Indicators are substances that change in physical appearance, e.g., color, at or approaching the endpoint of a chemical titration, e.g., on the passage between acidity and alkalinity. Reagents are substances used for the detection or determination of another substance by chemical or microscopical means, especially analysis. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. (From Grant & Hackh's Chemical Dictionary, 5th ed, p301, p499)

응용 분야

용도Tetraphenylphosphonium chloride is used to generate lipophilic salts from inorganic and organometallic anions. Thus, Ph4P+ is useful as a phase-transfer catalyst, again because it allows inorganic anions to dissolve in organic solvents.

제조 방법

Tetraphenylphosphonium chloride(PPh4Cl) and many analogous compounds can be prepared by the reaction of chlorobenzene with triphenylphosphine catalysed by nickel salts:PhCl + PPh3 → Ph4PCl