3-Butenenitrile → Butanenitrile, 4-(dichlorophenylsilyl)-

HRID 461576노트

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HRID 461576 반응식
[CH2:1]([C:4]#[N:5])[CH:2]=[CH2:3].[C:6]1([SiH:12]([Cl:14])[Cl:13])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>[Pt].[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[C:4]([CH2:1][CH2:2][CH2:3][Si:12]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([Cl:14])[Cl:13])#[N:5]

참가 물질

5

반응물 2

HCID 80093-ButenenitrileHCID 74207Dichloro(phenyl)silane

생성물 1

HCID 70649Butanenitrile, 4-(dichlorophenylsilyl)-

시약·촉매·용매 2

HCID 23939Platinum촉매HCID 61859Chloroplatinic acid촉매

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온도
120 °C

실험 절차

(γ-Cyanopropyl) phenyldichlorosilane was prepared by adding 67.1 grams (1.0 moles) of allylcyanide slowly to 177.1 grams (1.0 moles) of phenyldichlorosilane containing 10-4 moles of platinum as chloroplatinic acid at a temperature of 130° - 135° C. in a three-necked flask. After completion of the addition, the reaction mixture was heated at 120° C. for 16 hours. The pure (γ-cyanopropyl) phenyldichlorosilane was isolated by fractional distillation (b.p. 132° C./0.7 mm).

후처리

  1. custom(γ-Cyanopropyl) phenyldichlorosilane was prepared
  2. additionAfter completion of the addition

출처 및 근거

ORD 기록
ord-8063481af56440daac7e797b205c22f1
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04063911

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