Oxalic Acid → Vanadium hydroxide oxide phosphate

HRID 463534

반응식

HRID 463534 반응식
[P].[V:2].[P:3](=[O:7])([OH:6])([OH:5])[OH:4].C(O)(=O)C(O)=[O:10].[O-2:14].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5]>O>[OH-:4].[OH-:10].[OH-:14].[OH-:4].[OH-:4].[O-2:4].[O-2:4].[O-2:4].[O-2:4].[O-2:4].[O-:5][P:3]([O-:7])([O-:6])=[O:4].[O-:5][P:3]([O-:7])([O-:6])=[O:4].[O-:5][P:3]([O-:7])([O-:6])=[O:4].[O-:5][P:3]([O-:7])([O-:6])=[O:4].[O-:5][P:3]([O-:7])([O-:6])=[O:4].[V:2].[V:2].[V:2].[V:2].[V:2].[V:2]

참가 물질

7

반응물 5

HCID 971Oxalic AcidHCID 1004Phosphoric AcidHCID 23990VanadiumHCID 5462309PhosphorusHCID 178419084HCID 178419084, 화합물

생성물 1

HCID 6455080Vanadium hydroxide oxide phosphate

시약·촉매·용매 1

HCID 962Water용매2회

반응 조건

온도
80 °C

실험 절차

As an example of a starting material suitable for an amorphous complex oxide containing phosphorus and vanadium as the major constituents, a vanadyl phosphate solution was prepared. In 3.0 kg of deionized water, 2.956 kg of 85% phosphoric acid was dissolved, and 2.55 kg of oxalic acid (H2C2O4.2H2O) was further added and dissolved under heating. The solution was heated to 80° C., and 1.842 kg of vanadium pentoxide was gradually added and dissolved while paying a careful attention to the generation of bubbles. Then, the heating was continued for further 10 minutes under the boiling condition to complete the reduction. The solution was cooled, and deionized water was added to adjust the total amount to 10.00 kg, whereby the second component was obtained.

후처리

  1. dissolutiondissolved
  2. temperatureunder heating
  3. dissolutiondissolved
  4. temperatureThe solution was cooled
  5. additionwas added
  6. customwas obtained

출처 및 근거

ORD 기록
ord-36d45b67db0c4a2e94a2d0d00f0d23dd
출처 데이터셋
uspto-grants-1985_05
특허 번호
US04520127

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