Carbon Disulfide → 2-Methyl-3-hydroxy-4-mercaptomethyl-5-hydroxymethyl-6-vinylpyridine

반응식

[CH3:1][C:2]1[C:7]([OH:8])=[C:6]([CH2:9]O)[C:5]([CH2:11][OH:12])=[C:4]([CH:13]=[CH2:14])[N:3]=1.[OH-].[Na+].C(=S)=[S:18]>>[CH3:1][C:2]1[C:7]([OH:8])=[C:6]([CH2:9][SH:18])[C:5]([CH2:11][OH:12])=[C:4]([CH:13]=[CH2:14])[N:3]=1

참가 물질

반응물 3

HCID 6348Carbon Disulfide

HCID 14798Sodium Hydroxide

HCID 202640222-Methyl-3-hydroxy-4,5-di(hydroxymethyl)-6-vinylpyridine

생성물 1

HCID 202639312-Methyl-3-hydroxy-4-mercaptomethyl-5-hydroxymethyl-6-vinylpyridine

실험 절차

Treatment of the product of Step D with sodium hydroxide and carbon disulfide by the procedure described in Example 1, Step C, yields 2-methyl-3-hydroxy-4-mercaptomethyl-5-hydroxymethyl-6-vinylpyridine.

출처 및 근거

ORD 기록: ord-48ff85667c1c49b489847855e5f7b046
출처 데이터셋: uspto-grants-1985_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04546106

반응 노트

불러오는 중…