Triphenylphosphine → (Ethoxymethyl)(triphenyl)phosphanium chloride

HRID 46408

반응식

HRID 46408 반응식
[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:20]([O:22][CH2:23][Cl:24])[CH3:21]>C1C=CC=CC=1>[Cl-:24].[CH2:20]([O:22][CH2:23][P+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)[CH3:21]

참가 물질

4

반응물 2

HCID 11776TriphenylphosphineHCID 18523Chloromethyl ethyl ether

생성물 1

HCID 21470303(Ethoxymethyl)(triphenyl)phosphanium chloride

시약·촉매·용매 1

HCID 241Benzene용매

반응 조건

온도
84 °C

실험 절차

A solution of 99.66 g of triphenylphosphine and 37.82 g of chloromethyl ethyl ether in 240 ml of dry benzene was stirred and refluxed (84° C.) for 6 hours. The mixture then was chilled and filtered to give 7, as a white solid, mp 205°-206° C.

후처리

  1. temperatureThe mixture then was chilled
  2. filtrationfiltered
  3. customto give 7

출처 및 근거

ORD 기록
ord-3204c8b2736246ee820e2cf7f1906092
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04173463

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