1-Bromooctadecane → 3,5-Dioctadecyloxybenzoic acid ethyl ester

HRID 465877

반응식

HRID 465877 반응식
[CH2:1]([O:3][C:4](=[O:13])[C:5]1[CH:10]=[C:9]([OH:11])[CH:8]=[C:7]([OH:12])[CH:6]=1)[CH3:2].[CH2:14](Br)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].[Na]>C(O)C>[CH2:1]([O:3][C:4](=[O:13])[C:5]1[CH:10]=[C:9]([O:11][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH:8]=[C:7]([O:12][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH3:14])[CH:6]=1)[CH3:2]

참가 물질

5

반응물 3

HCID 82181-BromooctadecaneHCID 20098Benzoic acid, 3,5-dihydroxy-, ethyl esterHCID 5360545Sodium

생성물 1

HCID 537314753,5-Dioctadecyloxybenzoic acid ethyl ester

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

50 m mol of 3,5-dihydroxybenzoic acid ethyl ester, 120 m mol of stearyl bromide, and 110 m mol of sodium were made to react in ethanol, thereby forming 35 m mol of 3,5-dioctadecyloxybenzoic acid ethyl ester. This ester, 25 m mol, was first hydrolyzed into the corresponding acid, which in turn was converted into its acid chloride. The acid chloride was reacted in the same way as in Example 1, whereby 10 m mol of N-(3,5-dioctadecyloxybenzoyl)-N'methylsulfonyl-p-quinonediimine was obtained which is represented by the following formula: ##STR30##

출처 및 근거

ORD 기록
ord-0708f62d736c4ba789917a02358715dc
출처 데이터셋
uspto-grants-1992_10
특허 번호
US05153680

연결된 노트

불러오는 중…