Cyclohexanone → HCID 69497980, 화합물

HRID 495321

반응식

HRID 495321 반응식
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH-:8].[Na+].[CH2:10]([O:16][C:17]1[CH:24]=[CH:23][C:20]([CH:21]=O)=[CH:19][CH:18]=1)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>C(O)C.O>[CH2:10]([O:7][C:1]1[CH:6]=[CH:5][C:4]([CH:21]=[C:20]2[CH2:23][CH2:24][CH2:17][C:18](=[CH:21][C:20]3[CH:23]=[CH:24][C:17]([O:16][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])=[CH:18][CH:19]=3)[C:19]2=[O:8])=[CH:3][CH:2]=1)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

참가 물질

6

반응물 3

HCID 7967CyclohexanoneHCID 14798Sodium HydroxideHCID 79816p-(Hexyloxy)benzaldehyde

생성물 1

HCID 69497980HCID 69497980, 화합물

시약·촉매·용매 2

HCID 702Ethanol용매3회HCID 962Water용매

실험 절차

Cyclohexanone (2.6 ml, 0.025 mol) was dissolved in ethanol (5 ml), and was added to sodium hydroxide (0.38 g, 0.01 mol) dissolved in water (6 ml) and ethanol (2 ml) and was left to stir for 20 min. 4-Hexyloxybenzaldehyde (10 ml, 0.048 mol), dissolved in ethanol (40 ml), was added and the mixture was stirred at room temperature for 16 h. A yellow crystalline solid was isolated by vacuum filtration and was washed with cold ethanol and dried in a vacuum oven. Yield=4.32 g, 36%. 1H NMR and 13C NMR showed expected signals.

후처리

  1. additionwas added
  2. stirringthe mixture was stirred at room temperature for 16 h
  3. customA yellow crystalline solid was isolated by vacuum filtration
  4. washwas washed with cold ethanol
  5. customdried in a vacuum oven

출처 및 근거

ORD 기록
ord-affe587f4e1d4c599e66c79b12e2f716
출처 데이터셋
uspto-grants-2005_09
특허 번호
US06939479B2

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