N,N'-di-sec-butylidene-4,4'-methylenebis(2,6-diethylbenzeneamine) → N,N'-di-sec-butyl-4,4'-methylenebis(2,6-diethylbenzeneamine)

HRID 500032

반응식

HRID 500032 반응식
[C:1](=[N:5][C:6]1[C:11]([CH2:12][CH3:13])=[CH:10][C:9]([CH2:14][C:15]2[CH:20]=[C:19]([CH2:21][CH3:22])[C:18]([N:23]=[C:24]([CH2:26][CH3:27])[CH3:25])=[C:17]([CH2:28][CH3:29])[CH:16]=2)=[CH:8][C:7]=1[CH2:30][CH3:31])([CH2:3][CH3:4])[CH3:2]>[Pt].CC(C)=O>[CH:24]([NH:23][C:18]1[C:17]([CH2:28][CH3:29])=[CH:16][C:15]([CH2:14][C:9]2[CH:8]=[C:7]([CH2:30][CH3:31])[C:6]([NH:5][CH:1]([CH2:3][CH3:4])[CH3:2])=[C:11]([CH2:12][CH3:13])[CH:10]=2)=[CH:20][C:19]=1[CH2:21][CH3:22])([CH2:26][CH3:27])[CH3:25]

참가 물질

4

반응물 1

HCID 86608152N,N'-di-sec-butylidene-4,4'-methylenebis(2,6-diethylbenzeneamine)

생성물 1

HCID 66781129N,N'-di-sec-butyl-4,4'-methylenebis(2,6-diethylbenzeneamine)

시약·촉매·용매 2

HCID 23939Platinum촉매HCID 180Acetone용매

실험 절차

N,N′-di-sec-butylidene-4,4′-methylenebis(2,6-diethylbenzeneamine) (22.53 g) and Pt(S)/C (2.65 g) were added to acetone (34.0 g) in an autoclave. The closed autoclave was purged 3 times with 125 psig of H2 (9.63×105 Pa) at 22° C. The mixture was kept at 21° C. and 125 psi (8.62×105 Pa) of H2 for 6.5 hours, forming the corresponding N,N′-di-sec-butyl-4,4′-methylenebis(2,6-diethylbenzeneamine) quantitatively.

후처리

  1. customThe closed autoclave was purged 3 times with 125 psig of H2 (9.63×105 Pa) at 22° C
  2. customwas kept at 21° C.

출처 및 근거

ORD 기록
ord-89a1f47fe05b44cb85f0618e9dc4766f
출처 데이터셋
uspto-grants-2010_08
특허 번호
US07767858B2

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