Acetic Anhydride → HCID 15580722, 화합물
반응식
F[C:2](F)(F)[C:3]([NH:5][C:6]1[CH2:10][CH:9]([CH3:11])[N:8]([C:12]2[CH:17]=[CH:16][C:15](C(=O)C(F)(F)F)=[CH:14][CH:13]=2)[N:7]=1)=[O:4].C(OC(=O)C)(=O)C>CN(C)C1C=CN=CC=1.ClCCl>[CH3:11][CH:9]1[N:8]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[N:7]=[C:6]([NH:5][C:3](=[O:4])[CH3:2])[CH2:10]1참가 물질
5
실험 절차
A mixture of 2.0 g. of 3-amino-5-methyl-1-phenyl-2-pyrazoline (prepared in Example 5), 5.0 ml. of acetic anhydride and 100 mg. of 4-dimethylaminopyridine is allowed to stand at room temperature for 3 hours. The mixture is filtered to give a white solid. The solid is dissolved in dichloromethane and is columnized and recrystallized as for Example 14 (B) to give 0.90 g. of the desired product as colorless plates, m.p. 144.5°-146.5° C.
후처리
- additionA mixture of 2.0 g
- filtrationThe mixture is filtered
- customto give a white solid
- customto give 0.90 g
출처 및 근거
- ORD 기록
- ord-126f2227b75e4ea69b32c29420fcfdcf
- 출처 데이터셋
- uspto-grants-1984_05
- 특허 번호
- US04447442
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