Allyl bromide → Diethyl allylphosphonate

HRID 590892

반응식

[CH2:1](Br)[CH:2]=[CH2:3].[CH2:5]([O:7][P:8]([O:12]CC)[O:9][CH2:10][CH3:11])[CH3:6]>>[CH2:1]([P:8](=[O:12])([O:9][CH2:10][CH3:11])[O:7][CH2:5][CH3:6])[CH:2]=[CH2:3]

참가 물질

반응물 2

HCID 7841Allyl bromide

HCID 31215Triethyl phosphite

생성물 1

HCID 573014Diethyl allylphosphonate

실험 절차

Allyl bromide was treated with triethylphosphite in the absence of solvent using microwave conditions at 150° C. to give diethyl allylphosphonate. Diethyl allylphosphonate was combined with bromotrimethyl silane and subsequently quenched with methanol to afford diethyl allylphosphonic acid according to Scheme 7.

후처리

customat 150° C.

출처 및 근거

ORD 기록: ord-0e82b32ecb924645bc132c8becf71036
출처 데이터셋: uspto-grants-2016_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09234985B2

연결된 노트

불러오는 중…