Oxygen → Tridecanoic acid

HRID 597280

반응식

HRID 597280 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]CC.CN(C)[CH:17]=[O:18].[N+]([O-])([N+]([O-])=O)=[O:21].O=O.[O-2].[Ca+2]>C1C=CC=CC=1>[C:17]([OH:18])(=[O:21])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

참가 물질

7

반응물 5

HCID 977Oxygen2회HCID 6228DimethylformamideHCID 142601-TetradeceneHCID 25352Nitrogen oxide (N2O4)HCID 6850728Calciumoxide

생성물 1

HCID 12530Tridecanoic acid수율 92.4%

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

Tetradecene (19.8 grams, 0.1 mole) and dimethylformamide (20 milliliters, 0.26 mole) dissolved in 100 milliliters of benzene were treated with a 1:6 volume to volume ratio mixture of dinitrogen tetroxide (9.2 grams, 0.1 mole) and oxygen at 10° C. over a period of four hours and the mixture was swept with oxygen for an additional 15 minutes. Calcium oxide (5.6 grams, 0.1 mole) was added to the cooled stirred mixture and after 30 minutes, the solid material (37.6 grams) was separated by filtration and 300 milliliters of water were added thereto. After one hour at reflux, the solution was cooled and acidified with 6N hydrochloric acid to precipitate 19.8 grams (92 percent yield) of tridecanoic acid.

후처리

  1. customthe solid material (37.6 grams) was separated by filtration and 300 milliliters of water
  2. additionwere added
  3. temperatureAfter one hour at reflux
  4. temperaturethe solution was cooled

출처 및 근거

ORD 기록
ord-5ad06f5b9feb446a87ee6c447d58e99d
출처 데이터셋
uspto-grants-1977_03
특허 번호
US04013697

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