Eugenol → 4-Propylguaiacol
반응식
[C:1]1([O:11][CH3:12])[C:2](=[CH:4][CH:5]=[C:6]([CH:10]=1)[CH2:7][CH:8]=[CH2:9])[OH:3]>[C].[Pd].CC(O)C>[CH3:12][O:11][C:1]1[CH:10]=[C:6]([CH2:7][CH2:8][CH3:9])[CH:5]=[CH:4][C:2]=1[OH:3]참가 물질
4
실험 절차
Palladium-carbon (5 mass %, 54 mg) was added to a 2-propanol (2.5 mL) solution of eugenol (CAS No. 97-53-0, 500 mg) under an argon atmosphere. The resultant mixture was vigorously stirred at an external temperature of 50° C. under a hydrogen flow for about 4.5 hours. The reaction solution was filtered through Celite, and the filtrate was concentrated, to thereby obtain the title compound (447 mg) having the following physical properties.
후처리
- filtrationThe reaction solution was filtered through Celite
- concentrationthe filtrate was concentrated
출처 및 근거
- ORD 기록
- ord-4e043d5306dd4568b3fe3a8036310df1
- 출처 데이터셋
- uspto-grants-2011_03
- 특허 번호
- US07906549B2
반응 노트
불러오는 중…