Eugenol → 4-Propylguaiacol

HRID 602831

반응식

HRID 602831 반응식
[C:1]1([O:11][CH3:12])[C:2](=[CH:4][CH:5]=[C:6]([CH:10]=1)[CH2:7][CH:8]=[CH2:9])[OH:3]>[C].[Pd].CC(O)C>[CH3:12][O:11][C:1]1[CH:10]=[C:6]([CH2:7][CH2:8][CH3:9])[CH:5]=[CH:4][C:2]=1[OH:3]

참가 물질

4

반응물 1

HCID 3314Eugenol

생성물 1

HCID 177394-Propylguaiacol

시약·촉매·용매 2

HCID 178418390HCID 178418390, 화합물촉매HCID 3776Isopropanol용매

실험 절차

Palladium-carbon (5 mass %, 54 mg) was added to a 2-propanol (2.5 mL) solution of eugenol (CAS No. 97-53-0, 500 mg) under an argon atmosphere. The resultant mixture was vigorously stirred at an external temperature of 50° C. under a hydrogen flow for about 4.5 hours. The reaction solution was filtered through Celite, and the filtrate was concentrated, to thereby obtain the title compound (447 mg) having the following physical properties.

후처리

  1. filtrationThe reaction solution was filtered through Celite
  2. concentrationthe filtrate was concentrated

출처 및 근거

ORD 기록
ord-4e043d5306dd4568b3fe3a8036310df1
출처 데이터셋
uspto-grants-2011_03
특허 번호
US07906549B2

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