2-Methyl-1-nitroanthraquinone → 1-Amino-2-methylanthraquinone

HRID 614242

반응식

HRID 614242 반응식
[N+:1]([C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[C:9](=[O:19])[C:8]=2[CH:7]=[CH:6][C:5]=1[CH3:20])([O-])=O>O>[NH2:1][C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[C:9](=[O:19])[C:8]=2[CH:7]=[CH:6][C:5]=1[CH3:20]

참가 물질

3

반응물 1

HCID 314262-Methyl-1-nitroanthraquinone

생성물 1

HCID 67021-Amino-2-methylanthraquinone

시약·촉매·용매 1

HCID 962Water용매

실험 절차

The wet filter cake of 1-nitro-2-methylanthraquinone (0.45 mole) was placed in a 5 l flask. To the flask was added 420 g (1.75 mole) of Na2S.9H2O dissolved in 2.5 l of H2O and the slurry was heated and then stirred at 95°-99° C. for 2 hours. The reaction mixture was filtered and the orangish-red solid 1-amino-2-methylanthraquinone product was washed with hot H2O until the filtrate was clear and dried in vacuo at 70° C.

후처리

  1. temperaturethe slurry was heated
  2. filtrationThe reaction mixture was filtered
  3. washthe orangish-red solid 1-amino-2-methylanthraquinone product was washed with hot H2O until the filtrate
  4. customdried in vacuo at 70° C.

출처 및 근거

ORD 기록
ord-1fd157d502974679aba73837f1c364f2
출처 데이터셋
uspto-grants-1979_03
특허 번호
US04144252

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